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I can't tell you for sure. There are 2 things that might be called "lead free silver solder."
Low temperature "soft " solder for use with a soldering iron or electric soldering gun is a tin/silver alloy. It is very soft, very malleable. Common brands are "Tix" and "Sta-Brite."
Solder for use with a torch for "hard" soldering (or more accuratey "brazing") to assemble silver sheet and wire into jewelry is an alloy of silver, copper, zinc and, sometimes cadmium. Cadmium is much less common today because of safety concerns. Solder for brazing is much harder and stiffer than "Tix" or"Sta-Brite."
If the pendant is melted and puddled "lead free silver solder" then it is of the "Tix" or"Sta-Brite kind. If it is made from hard, stiff wire, then it is likely to be silver brazing solder.
Look at the definitions at
http://en.wikipedia.org/wiki/Solder for more details. You will have to ask your friend which kind of "lead free silver solder" they used.